Fakultät für Chemie - Department of Chemistry
 
 
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Bielefeld University > Department of Chemistry

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Finanzspritze für die Bielefelder Chemie

Der Fonds der Chemischen Industrie unterstützt die Fakultät für Chemie der Universität Bielefeld mit 84000 € zur Neuetablierung des Praktikums Biokatalyse in der stereoselektiven Synthese. Weiterlesen...

[Pressemitteilung des Fonds der Chemischen Industrie]


Current work from our research groups 


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The cover picture shows the window-like structure of [5.5.6.6]fenestranes as an outlook onto the slopes of the Teutoburger Wald near Bielefeld, Germany.
In an attempt to approach the – yet hypothetical – fully unsaturated tetrabenzo[5.5.5.5]fenestrene ("fenestrindene", top left in the clouds), bearing a flattened tetracoordinate carbon atom, via a – likewise hypothetical – phenanthro-annellated [5.5.5.5]fenestrane (top right), two novel diastereomeric [5.5.6.6]fenestranes were synthesized: The all-cis-benzodiphenanthro[5.5.6.6.]fenestrane ketone (bottom left) and the corresponding cis,cis,trans,cis isomer (bottom right). The cyclization reactions giving rise to these complex fenestrane frameworks involve unexpected stereoselectivity and ring sizes, as discussed in the article by D. Kuck et al. on p. 53 ff.


Alle GDCh-Vorträge


SFB 686

Model-Based Control of Homogenized Low-Temperature Combustion



Core Facility



FOR 945

Nanomagnete: von der Synthese über die Wechselwirkung mit Oberflächen zur Funktion